Hundreds of protesters battled police in the heart of Barcelona amid anger over the jailing of Catalan separatist leaders.
Masked protestors were seen blocking areas, damaging police vehicles, setting fire to large garbage bins, ransacking banks and attacking riot police officers with stones, cans and bottles.
Police responded with repeated volleys of foam bullets, smoke grenades, tear gas and water cannons.
The violence followed a largely peaceful demonstration that drew more than half a million people onto the streets of the Catalan capital.
Catalan interior affairs chief Miquel Buch distanced themselves from the riots, claiming "this kind of violence is unprecedented in Catalonia ... these people are not separatists".
Some 128 people have been arrested in the region over the past five days, with Spain's acting interior minister, Fernando Grande-Marlaska, warning that rioters faced up to six years in prison.
Israel said on Sunday it would halt military operations each day for 10 hours in parts of Gaza and allow new aid corridors in the enclave, where images of severely malnourished children have alarmed the world.
Firefighters battled wildfires across Turkey on Sunday amid a searing Mediterranean heat-wave, with authorities evacuating more than 3,600 people from settlements in two provinces.
The leaders of Thailand and Cambodia will attend mediation talks over their deadly border conflict in Malaysia on Monday, the Thai government said, even as both sides accused each other of launching fresh artillery strikes across contested areas.
Heavy rain around Beijing and across north and northeast China has killed two and forced thousands to relocate as authorities warned of further widespread rain and risks of disasters including landslides and flooding.
Firefighters were battling wildfires across Greece and the Western Balkans on Saturday as the south of Europe sweltered under the third heatwave of the summer, with some villages and settlements being evacuated in Greece and Albania.
Aid trucks started moving towards Gaza from Egypt, Al Qahera News TV said on Sunday, after months of international pressure and warnings from relief agencies about starvation spreading in the Palestinian enclave.
Israeli Prime Minister Benjamin Netanyahu and US President Donald Trump appeared to abandon Gaza ceasefire negotiations with Hamas, both saying it had become clear that the group did not want a deal.
Fighting on the Thai-Cambodian border extended into a third day and new flashpoints emerged on Saturday as both sides sought diplomatic support, saying they had acted in self-defence and calling on the other to cease fighting and start negotiations.
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Make sure to tune in every weekdays to Tag Gising Na from 5AM - 10 AM for a comprehensive roundup of important updates.
Welcome to Pinoy Bulletin, your go-to source for staying informed about important announcements, exciting group activities, community events, and job opportunities!
Make sure to tune in every weekdays to Tag Gising Na from 5AM - 10 AM for a comprehensive roundup of important updates.