Holders Liverpool crashed out of the Champions League after being taken to extra-time at Anfield.
Jurgen Klopp’s men lost 3-2 to Atletico Madrid in the second leg of their last-16 match.
Llorente scored a double and Alvaro Morata struck the decisive goal in the 120th minute to give the Spanish side a 4-2 aggregate victory.
Elsewhere, Paris Saint-Germain progressed to the quarter-finals with a 3-2 aggregate win over Borussia Dortmund.
Trailing 2-1 from the first leg in Dortmund, the Ligue 1 champions levelled the tie when Neymar netted just before the half-hour mark and Juan Bernat gave them the lead in first-half stoppage time.
Arsenal beat Chelsea 1-0 to reach League Cup final
Top-10 finishers in LIV events to receive word ranking points
Barca advance to Copa Del Rey semis as Albacete’s run ends
Morocco to appeal CAF rulings on disorderly AFCON final
Dupont back for France in Six Nations opener against Ireland
