Fifth-seeded Hubert Hurkacz has triumphed over fourth-seed Jannik Sinner 6-3 6-3 in the day's second quarter-final on centre court.
Earlier, second seed Andrey Rublev progressed beating Mackenzie McDonald 6-2 3-6 1-6.
The second semi-final places will go to the winners of the final two quarter-final matches, the first between top seed and world number one Novak Djokovic and qualifier Jiri Vesely, followed by Ricardas Berankis and sixth seed Denis Shapovalov.
Sinner, Medvedev and Sabalenka reach Wimbledon round three
Defending Wimbledon champion Jannik Sinner had several members of Europe's Ryder Cup team watching his second-round clash with Nuno Borges on Wednesday and in golfing parlance he kept it straight down the middle in a relatively risk-free victory.
Osaka brings the style again to beat Gasanova in Wimbledon second round
Four-times Grand Slam champion Naomi Osaka continued her impressive start to her Wimbledon campaign with a clinical 6-3 6-2 victory over Russian qualifier Anastasia Gasanova to reach the third round on a sunny Wednesday.
First-half goals send Mexico to comfortable 2-0 victory over Ecuador
Julian Quinones delivered a goal and an assist in the first half for Mexico, who maintained complete control in front of their vocal home fans to earn a 2-0 World Cup victory over Ecuador in a round of 32 match on Tuesday at Mexico City.
Mbappe scores twice as France ease past Sweden 3-0 to reach last 16
Kylian Mbappe scored twice as France swept aside Sweden 3-0 in the World Cup round of 32 on Tuesday, maintaining their perfect record of four wins from four and setting up a last-16 meeting with Paraguay.
Serena and Wawrinka go down fighting at Wimbledon
Serena Williams returned to competitive singles action on Tuesday amid huge fanfare after a four-year absence but the American icon could not overcome the first hurdle at Wimbledon and was beaten 6-3 6-7(6) 6-3 by Australian Maya Joint.
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Why did they choose bowling as their hobby, and what makes it unique compared to other activities?
